CALGON VESTAL LABORATORIES, DIV OF CALGON CORP -- NICKEL-SAFE ICE MACHINE CLEANER -- 6850-01-363-4770
===================== Product Identification ===================== Product ID:NICKEL-SAFE ICE MACHINE CLEANER MSDS Date:04/11/1991 FSC:6850 NIIN:01-363-4770 === Responsible Party === Company Name:CALGON VESTAL LABORATORIES, DIV OF CALGON CORP Address:5035 MANCHESTER AVE City:ST. LOUIS State:MO ZIP:63100 Country:US Info Phone Num:314-535-1395 (NIGHT) Emergency Phone Num:314-535-1810/800-424-9300(CHEMTREC) CAGE:21667 === Contractor Identification === Company Name:ALTER HARRY CO. Address:17725 VOLBERECHT Box:City:LANSING State:IL ZIP:60438-1555 Country:US Phone:312-243-5242 CAGE:70334 Company Name:CONVATEC, BRISTOL-MEYERS SQUIBB CO Address:7501 PAGE Box:147 City:ST. LOUIS State:MO ZIP:63166-1096 Country:US Phone:314-535-1810 (DAY) CAGE:21667 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: < 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CITRIC ACID CAS:77-92-9 RTECS #:GE7350000 Fraction by Wt: < 5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR PHOSPHORIC ACID IS 1 MG/M3. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-EYE:CORROSIVE.MAY CAUSE SEVERE IRRITATION,BURNS,PERMANENT TISSUE DAMAGE.SKIN:CORROSIVE.MAY CAUSE SEVERE IRRITATION.NO IMMEDIATE BURNING SENSATIONS MAY BE EXPECTED.INHALED:MAY CAUSE SEVERE RESPIR ATORY SYSTEM IRRITATION.ORAL:CORROSIVE.MAY CAUSE SEVERE DIGESTIVE SYSTEM IRRITATION & BURNS,TISSUE DAMAGE.CHRONIC-UNK. Effects of Overexposure:CORROSIVE.MAY CAUSE SEVERE EYE IRRITATION,BURNS,PERMANENT TISSUE DAMAGE.MAY CAUSE SEVERE SKIN IRRITATION.NO IMMEDIATE BURNING SENSATIONS MAY BE EXPECTED.MAY CAUSE SEVERE RESPIRATORY & DIGESTIVE SYSTEM S IRRITATION. SYMPTOMS MAY INCLUDE MOUTH& THROAT PAIN, NAUSEA, VOMITING POSSIBLY WITH FRESH BLOOD AND THIRST. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL ATTENTION IN ALL CASES.EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE CPR IF NEEDED.ORAL:DO NOT INDUCE VOMITING.IF CONSCIOUS,DRI NK 1-2 GLASSES OF WATER,MILK OR MILK OFMAGNESIA IF POSSIBLE.GET IMMEDIATE MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE AND/OR EXPLOSION HAZARDS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE GLOVES. MOP UP OR PICK UP WITH SAND OR CLAY. NEUTRALIZE WITH SODA ASH. REQUIRES GOOD VENTILATION AS CO2 IS PRODUCED. PLACE NEUTRALIZED SPILL IN DOT APPROVED DISPOSAL CONTAINER. FLUSH R ESIDUES WITH LARGE AMOUNT OF WATER TO DRAIN. Neutralizing Agent:SODA ASH ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN COOL,DRY AREA AWAY FROM ALKALIES.KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID BREATHING MISTS OR VAPORS. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF LEVELS EXCEED THE RECOMMENDED HEALTH STANDARDS, WEAR A NIOSH-APPROVED VAPOR RESPIRATOR FOR ACID. FOR EMERGENCY USE, WEAR A NIOSH APPROVED POSITIVE-PRESSURE MODE, SELF-CONTAINED BREATHING APPARATUS (SCBA). Ventilation:PROVIDE SUFFICIENT LOCAL EXHAUST VENTILATION TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL. Protective Gloves:NEOPRENE OR RUBBER Eye Protection:SAFETY GOGGLES & FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:>93.3C, 200.F Melt/Freeze Pt:=-17.8C, 0.F Spec Gravity:1.188 pH:<1 Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID - MILD CHEMICAL ODOR Percent Volatiles by Volume:30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES, AMMONIA, CHLORINE BLEACH Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:MAY FORM OXIDES OF PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.